Concept:Oxidation numbers are assigned using known values for other atoms and the overall charge on the ion.
Explanation:In this redox reaction, chromium changes from
Cr2O72− to
Cr3+.
Let the oxidation number of each Cr atom in
Cr2O72− be
x.
Oxygen has oxidation number
−2, and the total charge of the ion is
−2.
So:
2x+7(−2)=−2This gives
2x−14=−2Therefore
2x=12, so
x=+6.
On the product side, chromium appears as
Cr3+, so its oxidation number is
+3.
Thus, the oxidation number of chromium changes from
+6 to
+3.
Answer:+6 to
+3 (Option B).