Concept:An exterior angle of a regular polygon must divide 360∘ exactly because it equals n360∘ for some whole number n.Explanation:For a regular polygon with n sides, each exterior angle is given by:exterior angle=n360∘Thus, 360∘ must be perfectly divisible by the given angle.Check each option:360÷66=5.45, which is not a whole number.360÷72=5, so 72∘ is possible for a pentagon.360÷24=15, so 24∘ is possible.360÷15=24, so 15∘ is possible.Therefore, 66∘ cannot be an exterior angle of a regular polygon.Answer:A. 66∘