Concept:The principal functional group decides the parent name and receives the lowest locant.
Explanation:The compound
ClCH2CH2OH has a two-carbon chain derived from ethanol.
The hydroxyl group
−OH is the principal functional group, so the base name is ethanol.
Number the chain from the carbon attached to
−OH, making that carbon C-1.
The other carbon, which carries the chlorine atom, then becomes C-2.
Hence, the chloro substituent is located at position 2.
The correct IUPAC name is therefore 2-chloroethanol.
Answer:D. 2-chloroethanol