Concept:The sour taste of unripe fruits is caused by organic acids, which belong to the alkanoic acid family.Explanation:Unripe oranges contain citric acid, an organic acid.These acids contain the carboxyl functional group, −COOH.The −COOH group is responsible for the sour taste.Alkenes, alkanols, and alkanoates do not provide this sour taste.Answer:C. Alkanoic acid