Concept:Oxidation number is assigned using known charges, and the change reflects the electron gain by manganese.
Explanation:In
MnO4−, let the oxidation number of Mn be
x.
Oxygen has an oxidation number of
−2, and the total charge on the ion is
−1.
Therefore,
x+4(−2)=−1.
This gives
x−8=−1.
So,
x=+7.
Thus, Mn is in the
+7 oxidation state in
MnO4−.
On the product side, the species is
Mn2+, so the oxidation number of Mn is
+2.
Hence, the oxidation number of manganese changes from
+7 to
+2.
Answer:The oxidation number changes from
+7 to
+2.