Concept:Most chloride salts are soluble in water, but silver chloride is a well-known exception.Explanation:Silver chloride, AgCl, is insoluble in water because its crystal lattice is very strong.Alkali metal and ammonium chlorides, such as KCl and NH4Cl, dissolve readily in water.Zinc chloride, ZnCl2, is also soluble in water.Therefore, the only insoluble chloride among the given options is AgCl.Answer:A. AgCl