Concept:The enzyme that phosphorylates glucose at the start of glycolysis is hexokinase.Explanation:In the first step of glycolysis, glucose is phosphorylated by ATP to form glucose-6-phosphate.The reaction is: Glucose+ATP→Glucose-6-phosphate+ADPThis phosphorylation is catalysed by the enzyme hexokinase.Therefore, the correct option is C.Answer:C. hexokinase