Concept:Boyle's law states that for a fixed mass of gas at constant temperature, pressure and volume are inversely proportional.Explanation:The mathematical relationship is P1V1=P2V2.Initial conditions: P1=2.0atm and V1=4.0L.Final pressure: P2=1.0atm; final volume V2 is unknown.Substitute the values: (2.0)(4.0)=(1.0)(V2).Solve for V2: V2=1.02.0×4.0=8.0L.Since the pressure is reduced to half, the volume should double, which matches this result.Answer:The new volume of the gas is 8.0L, so the correct option is C.