Concept:Charles's law states that at constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature.Explanation:First, convert the temperatures from Celsius to Kelvin:T1=0∘C+273=273KT2=15∘C+273=288KUsing Charles's law formula:T1V1=T2V2Make V2 the subject of the formula:V2=T1V1×T2Substitute the given values:V2=27329.5×288=31.1cm3Answer:The volume of the gas at 15∘C is 31.1cm3.Therefore, the correct option is D.