Concept:A more reactive metal displaces a less reactive metal from its salt solution.
Explanation:Copper sulphate solution contains
Cu2+ ions.
To recover copper, the metal added must be higher than copper in the electrochemical series.
Iron is more reactive than copper, so it donates electrons and reduces
Cu2+ to copper metal.
The equation is:
Fe(s)+CuSO4(aq)→FeSO4(aq)+Cu(s).
Ionic form:
Fe(s)+Cu2+(aq)→Fe2+(aq)+Cu(s).
Sodium reacts violently with water instead of displacing copper.
Silver and mercury are less reactive than copper, so they cannot displace it.
Therefore, iron is the correct metal for this recovery.
Answer:D. Fe