Concept:At constant volume and temperature, the pressure of a gas is directly proportional to the number of moles present.
Explanation:From the ideal gas equation,
PV=nRT.
Since the container volume,
V, and temperature,
T, remain unchanged, pressure depends only on the amount of gas,
n.
If the quantity of oxygen is reduced by one-half, then
n2=2n1.
Thus, the pressure is also halved:
P2=2P1.
Substituting the given pressure,
P2=20.825 atm.
P2=0.4125 atm≈0.413 atm.
Therefore, the remaining gas exerts a lower pressure, not a higher one, because the number of gas particles has decreased.
Answer:C. 0.413 atm