Concept: Alkoxyalkanes are ethers with the general formula
R−O−R′, so count the distinct ways to split 4 carbon atoms between
R and
R′.
Explanation:The formula
C4H10O has no double bonds or rings, so it represents a saturated ether.
The two alkyl groups attached to oxygen must together contain exactly 4 carbon atoms.
Case 1: methyl (
1 carbon) combined with a propyl group (
3 carbons).
The propyl group can be either n-propyl or isopropyl, giving two different alkoxyalkanes: methoxypropane and methoxyisopropane.
Case 2: ethyl (
2 carbons) combined with another ethyl group (
2 carbons).
This gives only one alkoxyalkane: ethoxyethane.
No other combination of alkyl groups has a total of 4 carbon atoms.
Therefore, the total number of possible alkoxyalkanes is
2+1=3.
Answer: D. 3