Concept:Isoelectronic ions have the same number of electrons and the same electronic arrangement.Explanation:Find the electron count of each ion.Na+: atomic number 11, so 11−1=10 electrons; configuration 2,8.Mg2+: atomic number 12, so 12−2=10 electrons; configuration 2,8.O2−: atomic number 8, so 8+2=10 electrons; configuration 2,8.Si2+: atomic number 14, so 14−2=12 electrons; configuration 2,8,2.Three ions have 10 electrons, but Si2+ has 12 electrons.Thus, Si2+ is not isoelectronic with the others.Answer:C. Si2+