Concept:Tollen's reagent distinguishes aldehydes from ketones.Explanation:CH3CH2CHO is an aldehyde, while CH3COCH3 is a ketone.Aldehydes reduce Tollen's reagent, producing a silver mirror.Ketones do not react with Tollen's reagent under mild conditions.Therefore, the two compounds can be distinguished by Tollen's reagent.Answer:C. Tollen's reagent