Concept:Permanent hardness is caused by dissolved chlorides and sulphates of calcium and magnesium, and it can be removed using sodium carbonate (Na2CO3).Explanation:Sodium carbonate, also known as washing soda or soda ash, reacts with these dissolved salts to form insoluble carbonates.For example: CaCl2+Na2CO3→CaCO3↓+2NaCl.The insoluble carbonates, such as CaCO3 and MgCO3, can be removed by filtration, leaving the water soft.Thus, sodium carbonate (Na2CO3) is the chemical used to remove permanent hardness.Answer:Option B: Na2CO3