Concept:Percentage is calculated as totalpart×100%.Here, the part is the walking time and the total is the whole journey time.Explanation:First, convert the mixed fractions into improper fractions.Walking time: 2221=222×2+1=245 minutes.Running time: 721=27×2+1=215 minutes.Total time taken to reach school:245+215=260=30 minutes.Now, find the percentage of total time spent walking.Percentage of walking =30245×100%=245×301×100%=2×3045×100%=604500%=75%.So, John spends 75% of the total time walking.Answer:75%, which is option D.